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OUR RESEARCH

First-level organometallic chemistry topics

Our reseach focuses on the development of early-transition organometalic systems which are involved in the activation of small molecules. Particular enphasis is devoted to N2, although we have interest in other small molecules such as H2 or CO2 in order to synthesize high-value products. This research is of great value for our students, who do in-depth research and develop their expertise in synthesis, catalysis and spectroscopy during their internship in our group.

Click below to learn more about our research lines:

- Dinitrogen fixation, activation and functionalization.

- Organometallic catalysis.

- Redox active ligands.

- Reactivity of polymetallic complexes.

LATEST PUBLICATIONS

“Pentamethylcyclopentadienyltrimethylgermane: A Nontoxic Entry to Mid-Valent Monopentamethylcyclopentadienylvanadium Chloride Complexes” A Calvo-Molina, A. Pérez-Redondo, C. Yélamos,  Organometallics 2024, 43, 1780–1784.


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“A Mixed-Valence Ti(II)/Ti(III) Inverted Sandwich Compound as a Regioselective Catalyst for the Uncommon 1,3,5-Alkyne Cyclotrimerization”  E. Álvarez-Ruiz, I. Sancho, M. Navarro, I. Fernández, C. Santamaría, A. Hernán-Gómez, Inorg. Chem. 2024, 63, 8642–8653.

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“Half-Sandwich Zirconium and Hafnium Amidoborane Complexes: Precursors of Hydride Derivatives”  M. Greño, A. Pérez-Redondo, J. Torrijos, V. Varela-Izquierdo, C. Yélamos, Inorg. Chem. 2024, 63, 6576–6588.

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“Synthetic Studies and Structural Aspects of Dinuclear Sulfur Titanium Compounds”  E. Álvarez-Ruiz, J.I. González-Pérez, A. Hernán-Gómez, A. Martín, M- Mena, C. Santamaría, Eur. J. Inorg. Chem. 2024, e202400. 

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Metallocubanes Research Group
Organic and Inorganic Chemistry Department, Pharmacy Faculty
University Campus, Crta. Madrid-Barcelona km 33.6
28805 - Alcalá de Henares, Madrid (Spain)

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